Publications
2024
Superhydrophobic Metal−Organic Framework-Based Composite Featuring Removal of Hydrophobic Drugs and Pesticides and Antibacterial Activities
A. Rana, S. Ghosh, A. Patel, A. Das, A. Bhunia, D. Manna, D. Volkmer, S. Biswas
Inorg. Chem. 2024, 63, 15311-15322
DOI: 10.1021/acs.inorgchem.4c02005
Exploring Dipolar Dynamics and Ionic Transport in Metal-Organic Frameworks: Experimental and Theoretical Insights
R. Freund, A. Schulz, P. Lunkenheimer, M. Kraft, T. Bergler, H. Oberhofer, D. Volkmer
Adv. Funct. Mater. 2024, 2415376
DOI: 10.1002/adfm.202415376
Naphthalimide functionalized metal–organic framework for rapid and nanomolar level detection of hydrazine and anti-hypertensive drug nicardipine
S. S. Hossain, D. Volkmer, S. Biswas
Dalton Trans. 2024, 53, 8812-8822
DOI: 10.1039/D4DT00818A
Enantioselective Enrichment of Chiral 1-Phenylethanol in the Camphor-Based Chiral Metal-Organic Framework CFA-22
R. Röß-Ohlenroth, K. Knippen, M. Kraft, D. Volkmer
CrystEngComm 2024, 26, 2051–2055
DOI: 10.1039/D4CE00181H
Heteropentanuclear {Ru(II)Cu(II)4} Kuratowski Complexes Assembled from a Ruthenium(II) Precursor Complex to Study Competing Exchange Interactions in M(II)(ta)2 Networks [ta(−) = 1,2,3- Triazolate]
W. G. Daul, M. Hirrle, B. Eisfeld, M. Kraft, H.-A. Krug von Nidda, D. Volkmer
Inorg. Chem. 2024, 63, 5027–5039
DOI: 10.1021/acs.inorgchem.3c04478
2023
Critical Perspectives on Metal−Organic Frameworks and Their Composites for the Adsorptive Removal of Antibiotics from Wastewater Matrices
D. Mukherjee, J. Behera, S. Mondal, S. C. Pal, D. Volkmer, M. C. Das
Cryst. Growth Des. 2023, 11, 7612–7634
DOI: 10.1021/acs.cgd.3c00892
Benzothiadiazole-based rotation and possible antipolar order in carboxylate-based metal-organic frameworks
J. Schnabel, A. Schulz, P. Lunkenheimer, D. Volkmer
Commun. Chem. 2023, 6, 161
DOI: 10.1038/s42004-023-00959-6
2H NMR studies on the dynamics of supercooled water in a metal–organic framework
V. Schiller, K. Knippen, A. Loidl, P. Lunkenheimer, D. Volkmer, M. Vogel
J. Chem. Phys. 2023, 159, 034501
DOI: 10.1063/5.0159256
MOFs for long-term gas storage: exploiting kinetic trapping in ZIF-8 for on-demand and stimuli-controlled gas release
K. Heinz, S. M. J. Rogge, A. Kalytta-Mewes, D. Volkmer, H. Bunzen
Inorg. Chem. Front. 2023, 10, 4763-4772
DOI: 10.1039/d3qi01007d
Unveiling the atomistic and electronic structure of NiII–NO adduct in a MOF-based catalyst by EPR spectroscopy and quantum chemical modelling
K. Thangavel, P. C. Bruzzese, M. Mendt, A. Folli, K. Knippen, D. Volkmer, D. M. Murphy, A. Pöppl
Phys. Chem. Chem. Phys. 2023, 25, 15702-15714
DOI: 10.1039/d3cp01449e
Frustration on a centered pyrochlore lattice in metal-organic frameworks
R. P. Nutakki, R. Röß-Ohlenroth, D. Volkmer, A. Jesche, H.-A. Krug von Nidda, A. A. Tsirlin, P. Gegenwart, L. Pollet, L. D. C. Jaubert
Phys. Rev. Research 2023, 5, L022018
DOI: 10.1103/PhysRevResearch.5.L022018
2022
Inhibition, Binding of Organometallics, and Thermally Induced CO
Release in an MFU-4-Type Metal−Organic Framework Scaffold with
Open Bidentate Bibenzimidazole Coordination Sites
R. Röß-Ohlenroth, M. Kraft, H. Bunzen, D. Volkmer
Inorg. Chem. 2022, 61, 41, 16380–16389
DOI: 10.1021/acs.inorgchem.2c02394
Tridecacyclene Tetraimide: An Easily Reduced Cyclooctatetraene Derivative
R. Kumar, P. J. Chmielewski, T. Lis, D. Volkmer, M. Stepie´n
Angew. Chem. Int. Ed. 2022, 61, e202207486
DOI: 10.1002/anie.202207486 or DOI: 10.1002/ange.202207486 (German Edition)
Anionic or neutral? The charge of Ni8 cubes in metal-organic framework compounds.
R. Freund, A. Kalytta-Mewes, M. Kraft, D. Volkmer
Chem. Commun. 2022, 58, 9349–9352
DOI: 10.1039/D2CC03016K
Study of Surfactant-Induced Deformations at the Interface of Emulsion Droplets by Digital Image Analysis of Droplet Projections
H. vom Stein, D. Volkmer
Adv. Mater. Interfaces 2022, 2200264
DOI: 10.1002/admi.202200264
Combining Theory and Experiments To Study the Influence of Gas Sorption on the Conductivity Properties of Metal–Organic Frameworks
C. Muschielok, A. Reiner, R. Röß-Ohlenroth, A. Kalytta-Mewes, D. Volkmer, A. Wixforth, H. Oberhofer
ACS Appl. Mater. Interfaces, 2022, 14, 29, 33662–33674
DOI: 10.1021/acsami.2c05127
Synthesis, Thermal Stability and Magnetic Properties of an Interpenetrated Mn(II) Triazolate Coordination Framework
R. Röß-Ohlenroth, M. Hirrle, M. Kraft, A. Kalytta-Mewes, A. Jesche, H.-A. Krug von Nidda, D. Volkmer
Z. Anorg. Allg. Chem., 2022, 648, e202200153
DOI: 10.1002/zaac.202200153
Synthesis, Thermal Stability and Magnetic Properties of an Interpenetrated Mn(II) Triazolate Coordination Framework
R. Röß-Ohlenroth, M. Hirrle, M. Kraft, A. Kalytta-Mewes, A. Jesche, H.-A. Krug von Nidda, D. Volkmer
Z. Anorg. Allg. Chem., 2022, accepted
DOI: 10.1002/zaac.202200153
Viscoelasticity and energy dissipation as indicators of flexural fatigue behavior in a ductile carbon fiber-reinforced cementitious composite
M. Rutzen, D. Volkmer
Int. J. Fatigue, 2022, 160, 106839
DOI: 10.1016/j.ijfatigue.2022.106839
Assembly of Porous Metal Hydrogen-Bonded Organic Frameworks from Diamine-Functionalized Kuratowski Complexes
R. Röß-Ohlenroth, C. Freudig, M. Kraft, H. Bunzen, D. Volkmer
Cryst. Growth Des., 2022, 22, 379-391
DOI: 10.1021/acs.cgd.1c01008
Influencing the Dimensionality of Ni/Co-Bipyrazole based Coordination Frameworks through Anions and thermal Activation
R. Freund, M. Kraft, D. Volkmer
Eur. J. Inorg. Chem., 2022, e202100853
DOI: 10.1002/ejic.202100853
2021
3D printing as an automated manufacturing method for a carbon fiber-reinforced cementitious composite with outstanding flexural strength (105 N/mm2)
M. Rutzen, M. Schulz, J. Moosburger-Will, P. Lauff, O. Fischer, D. Volkmer
Mater Struct 2021, 54:234
DOI: 10.1617/s11527-021-01827-2
Evaluation of the Behavior of Carbon Short Fiber Reinforced Concrete (CSFRC) Based on a Multi-Sensory Experimental Investigation and a Numerical Multiscale Approach
P. Lauff, P. Pugacheva, M. Rutzen, U. Weiss, O. Fischer, D. Volkmer, M. A. Peter, C. U. Grosse,
Materials 2021, 14, 7005
DOI: 10.3390/ma14227005
Acenaphtho[1,2-d][1,2,3]triazole and Its Kuratowski Complex. A
π-Extended Tecton for Supramolecular and Coordinative Selfassembly
K. Knippen, D. Matuszczyk, M. Kraft, B. Bredenkötter, G. Eickerling, T. Lis,
D. Volkmer, M. Stępień
Chem. Eur. J. 2021, accepted
DOI: 10.1002/chem.202103480
Interfacial Instability as Shaping Mechanism for Polystyrene Particles with Tunable Surface Texture
H. vom Stein, D. VolkmerAdv. Mater. Interfaces 2021, 2100628
DOI: 10.1002/admi.202100628
Influence of fiber alignment on pseudoductility and microcracking in a cementitious carbon fiber composite material
M. Rutzen, P. Lauff, R. Niedermeier, O. Fischer, M. Raith, C. U. Grosse, U. Weiss, M. A. Peter, D. VolkmerMater. Struct. 2021, 54:58
DOI: 10.1617/s11527-021-01649-2
A Zr-Based Metal-Organic Framework with DUT-52 Structure Containing a Trifluoroacetamido Functionalized Linker for Aqueous Phase Fluorescence Sensing of Cyanide Ion and Aerobic Oxidation of Cyclohexane
C. Gogoi, N. Nagarjun, S. Roy, M. SK, D. Volkmer, A. Dhakshinamoorthy, S. Biswas
Inorg. Chem. 2021, 60, 4539-4550
DOI: 10.1021/acs.inorgchem.0c03472
An Anthracene‐Based Metal‐Organic Framework for Selective Photo‐Reduction of Carbon Dioxide to Formic Acid Coupled with Water Oxidation
M. SK, S. Barman, S. Paul, R. De, S. S. Sreejith, H. Reinsch, M. Grzywa, N. Stock, D. Volkmer, S. Biswas, S. Roy
Chem. Eur. J. 2021, 27, 4098-4107
DOI: 10.1002/chem.202004596
2020
CFA-18: a homochiral metal–organic framework (MOF) constructed from rigid enantiopure bistriazolate linker molecules
K. Knippen, B Bredenkoetter, L. Kanschat, M. Kraft, T. Vermeyen, W. Herrebout, K. Sugimoto, P. Bultinck, D. Volkmer
Dalton Trans. 2020, 49, 15758-15768
DOI: 10.1039/d0dt02847a
Influence of surface-modification, length and volume fraction of carbon
short fibers on the mechanical properties of calcium aluminate
cement systems
P. Beroll, S. Schmalzl D. Volkmer
Mater. Today Commun. 2020, 25, 101704
DOI: 10.1016/j.mtcomm.2020.101704
Cooperative Large-Hysteresis Spin-Crossover Transition in the Iron(II) Triazolate [Fe(ta)2] Metal–Organic Framework
M. Grzywa, R. Röß-Ohlenroth, C. Muschielok, H. Oberhofer, A. Błachowski, J. Żukrowski, D. Vieweg, H.-A. Krug von Nidda, D. Volkmer
Inorg. Chem. 2020, 59, 10501-10511
DOI: 10.1021/acs.inorgchem.0c00814
Supercooled water confined in a metal-organic framework
J. K. H. Fischer, P. Sippel, D. Denysenko, P. Lunkenheimer, D. Volkmer, A. Loidl
Commun. Phys. 3, 95 , 2020
DOI: 10.1038/s42005-020-0363-x
Indications for Lifshitz transitions in the nodal-line semimetal ZrSiTe induced by interlayer interaction
M. Krottenmüller, M. Vöst, N. Unglert, J. Ebad-Allah, G. Eickerling, D. Volkmer, J. Hu, Y. L. Zhu, Z. Q. Mao, W. Scherer, C. A. Kuntscher
Phys. Rev. B 101, 081108(R)
DOI: 10.1103/PhysRevB.101.081108
Multi-component inorganic anchoring system bases on fine aluminous cement
A. Pfeil, V. Sirch, M. Schönlein, P. Beroll, D. Volkmer
Patent WO2020074345A1, 2020
Mehrkomponentiges anorganisches Verankerungssystem auf Basis von feinem alaunhaltigem Zement
P. Beroll, A. Pfeil, V. Sirch, M. Schönlein, D. Volkmer
Patent EP3636618A1, 2020
Zweikomponentiges anorganisches Injektionsmörtelsystem auf Basis von Feintonerdzement mit erhöhten Belastungswerten
P. Beroll, A. Pfeil, M. Schönlein, D. Volkmer
Patent EP3636619A1, 2020
Verfahren zur Herstellung einer Struktur aus Mörtel oder Beton und dazu geeignete Anordnung
M. Hambach, D. Volkmer
Patent EP3141362B1, 2020
2019
Zementgebundener kohlenstoffaserverstärkter Hochleistungswerkstoff (Carbonkurzfaserbeton), Abschlussbericht
O. Fischer, D. Volkmer, P. Lauff, M. Hambach, M. Rutzen
Forschungsinitiative Zukunft Bau, Förderkennzeichen: SWD-10.08.18.7-16.33, Fraunhofer IRB Verlag 2019, ISBN: 978-3-7388-0422-5
CFA-15 – a perfluorinated metal–organic framework with linear 1-D CuII-chains containing accessible unsaturated, reactive metal centres
J. Fritzsche, R. Ettlinger, M. Grzywa, S. G. Jantz, A. Kalytta-Mewes, H. Bunzen, H. A. Höppe, D. Volkmer
Dalton Trans., 2019, 48, 15236-15246
DOI: 10.1039/c9dt02133g
Synthesis,thermal stability and magnetic properties of Mn(II)coordination framework containing bistriazolateligands
H. Bunzen, M. Grzywa, R. Aljohani, H.-A. Krug von Nidda, D. Volkmer
Eur. J. Inorg. Chem., 2019, 4471-4476
DOI: 10.1002/ejic.201900796
Microstructural analysis of crack growth caused by static and dynamic loads in a carbon fiber reinforced cement paste
M. Rutzen, D. Volkmer, U. Weiß, L. Reischmann, M. A. Peter, P. Lauff, O. Fischer; M. Raith, C. Große
Advances in Engineering Materials, Structures and Systems: Innovations, Proceedings of the 7th International Conference on Structural Engineering, Mechanics and Computation (SEMC 2019), September 2-4, 2019, Cape Town, South Africa
A. Zingoni (Editor), pp. 231 - 232 (physical edition), pp. 617 - 622 (ebook), ISSN: 978-1-138-38696-9
Long-term entrapment and temperature-controlled-release of SF6 gas in metal–organic frameworks (MOFs)
H. Bunzen, A. Kalytta-Mewes, L. van Wüllen, D. Volkmer
Beilstein J. Nanotechnol., 2019, 10, 1851-1859
DOI: 10.3762/bjnano.10.180
Organometallic MFU-4l(arge) metal-organic frameworks
R. Röß-Ohlenroth, B. Bredenkötter, D. Volkmer
Organometallics, 2019, 38, 3444-3452
DOI: 10.1021/acs.organomet.9b00297
Zeolitic Imidazolate Framework‐8 as pH‐sensitive Nanocarrier for ‘Arsenic Trioxide’ Drug Delivery
R. Ettlinger, N. Moreno, D. Volkmer, K. Kerl, H. Bunzen
Chem. Eur. J., 2019, 25, 13189–13196
DOI: 10.1002/chem.201902599
Dynamic Studies on Kinetic H2/D2 Quantum Sieving in a Narrow Pore Metal‒Organic Framework Grown on a Sensor Chip
B. Paschke, D. Denysenko, B. Bredenkötter, G. Sastre, A. Wixforth, D. Volkmer
Chem. Eur. J., 2019, 25, 10803-10807
DOI: 10.1002/chem.201900889
Investigation of Localized Damage Indicators of a Carbon Short-Fibre Reinforced High Performance Concrete under Dynamic and Flexural Load
P. Lauff, M. Raith, C. Große, M. Rutzen, D. Volkmer, L. Reischmann, U. Weiß, M. A. Peter, O. Fischer
Proceedings of the fib Symposium 2019
Concrete - Innovations in Materials, Design and Structures, pp. 1952-1959, ISSN: 2617-4820
'BASF Award for the best young researcher of the Symposium'
Single crystals of metal-organic framework Ulm-4 grown selectively on a micro-structured plasma polymer coating
A. Schaller, A. Ullrich, D. Volkmer
Thin Solid Films, 2019, 684, 36-41
DOI: 10.1016/j.tsf.2019.05.050
Anisotropic Water-Mediated Proton Conductivity in Large Iron(II)Metal−Organic Framework Single Crystals for Proton-Exchange
H. Bunzen, A. Javed, D. Klawinski, A. Lamp, M. Grzywa, A. Kalytta-Mewes, M. Tiemann, H.-A. Krug von Nidda, T. Wagner, D. Volkmer
Appl. Nano Mater. 2019, 2, 291-298.
DOI: 10.1021/acsanm.8b01902
Glycerol confined in zeolitic imidazolate frameworks: The temperature-dependent cooperativity length scale of glassy freezing
M. Uhl, J.K.H. Fischer, P. Sippel, H. Bunzen, P. Lunkenheimer, D. Volkmer, A. Loidl
J. Chem. Phys. 2019, 150, 024504.
DOI: 10.1063/1.5080334
Properties of 3D-printed fiber-reinforced Portland cement paste
M. Hambach, M. Rutzen, D. Volkmer in 3D Concrete Printing Technology, Chapter 5, Butterworth-Heinemann Inc 2019, Ch. 5; ISBN: 978-0-12-815481-6.
Metal–organic frameworks in Germany: From synthesis to function
J.D. Evans, B. Garai, H. Reinsch, W. Li, S. Dissegna, V. Bon, I. Senkovska, R.A. Fischer, S. Kaskel, C. Janiak, N. Stock, D. Volkmer
Coord. Chem. Rev. 2019, 380, 378-418.
DOI: 10.1016/j.ccr.2018.10.002
2018
Metal-organic framework nanoparticles for arsenic trioxide drug delivery
R. Ettlinger, M. Sönksen, M. Graf, N. Moreno, D. Denysenko, D. Volkmer, K. Kerl, H. Bunzen
J. Mater. Chem. B, 2018, 6, 6481-6489.
DOI: 10.1039/C8TB01899E
CFA-14 – a perfluorinated metal–organic framework with linear 1-D CoIIchains showing temperature dependent spin-chain magnetic ordering
J. Fritzsche, M. Grzywa, D. Denysenko, S. Reschke, K. Sugimoto, H.-A. Krug von Nidda, D. Schmidtner, D. Volkmer
Dalton Trans., 2018, 47, 12750-12756
DOI: 10.1039/C8DT02841A
Dielectric properties of confined ionic liquids
P. Sippel, D. Denysenko, D. Volkmer, S. Krohns
Proceedings of the 12th Pacific Rim Conference on Ceramic and Glass Technology: Ceramic Transactions 2018, 264.
DOI: 10.1002/9781119494096.ch19
Achieving Large Volumetric Gas Storage Capacity in Metal−Organic Frameworks by Kinetic Trapping: A Case Study of Xenon Loading in MFU‑4
H. Bunzen, F. Kolbe, A. Kalytta-Mewes, G. Sastre, E. Brunner, D. Volkmer
J. Am. Chem. Soc., 2018, 140, 10191–10197
DOI: 10.1021/jacs.8b04582
Synthesis and characterization of a flexible metal-organic framework generated from MnIII and the 4,4’-bipyrazolate-ligand
S. Spirkl, M. Grzywa, D. Volkmer
Dalton Trans., 2018, 47, 8779-8786
DOI: 10.1039/c8dt01185k
High Volumetric Hydrogen Storage Capacity using Interpenetrated Metal–Organic Frameworks
R. Balderas-Xicohténcatl, P. Schmieder, D. Denysenko, D. Volkmer, M. Hirscher
Energy Technol. 2018, 6, 510-512
DOI: 10.1002/ente.201700608
2017
Zinc(II) Coordination Frameworks Based on Benzobisimidazole: The Role of the Methyl Substituent
H. Bunzen, F. Mahmood, M. Grzywa, D. Volkmer
Eur. J. Inorg. Chem., 2017, 5395-5402
DOI: 10.1002/ejic.201701015
Defibrillation of soft porous metal-organic frameworks with electric fields
A. Knebel, B. Geppert, K. Voglmann, D.I. Kolkolov, A.G. Stepanov, J. Twiefel, P. Heitjans, D. Volkmer, J. Caro
Science, 2017, 358 (6361), 347-351
DOI: 10.1126/science.aal2456
CFA-13 - a bifunctional perfluorinated metal-organic framework featuring active Cu(I) and Cu(II) sites
J.C. Fritzsche, D. Denysenko, M. Grzywa, D. Volkmer
Dalton Trans., 2017, 46, 14907-14915
DOI: 10.1039/C7DT02512B
Magnetodielectric coupling in a non-perovskite metal-organic framework
T. Basu, A. Jesche, B. Bredenkötter, M. Grzywa, D. Denysenko, D. Volkmer, A. Loidl, S. Krohns
Mater. Horiz., 2017, 4, 1178-1184
DOI: 10.1039/C7MH00716G
Single-Crystal to Single-Crystal Transformation of a Nonporous Fe(II) Metal–Organic Framework into a Porous Metal–Organic Framework via a Solid-State Reaction
S. Spirkl, M. Grzywa, S. Reschke, J.K.H. Fischer, P. Sippel, S. Demeshko, H.-A. Krug von Nidda, D. Volkmer
Inorg. Chem., 2017, 56, 12337–12347
DOI: 10.1021/acs.inorgchem.7b01818
Bistriazole-p-benzoquinone and its alkali salts: electrochemical behaviour in aqueous alkaline solutions
H. Bunzen, A. Lamp, M. Grzywa, C. Barkschat, D. Volkmer
Dalton Trans., 2017, 46, 12537-12543
DOI: 10.1039/C7DT02803B
Preparation of thick silica coatings on carbon fibers with fine-structured silica nanotubes induced by a self-assembly process
B. Baumgärtner, H. Möller, T. Neumann, D. Volkmer
Beilstein J. Nanotechnol. 2017, 8, 1145–1155
DOI: 10.3762/bjnano.8.116
Fast Surface Acoustic Wave-Based Sensors to Investigate the Kinetics of Gas Uptake in Ultra-Microporous Frameworks
B. Paschke, A. Wixforth, D. Denysenko, D. Volkmer
ACS Sens., 2017, 2, 740-747
DOI: 10.1021/acssensors.7b00014
CFA-4 - a fluorinated metal-organic framework with exchangeable interchannel cations
J. Fritzsche, M. Grzywa, D. Denysenko, V. Bon, I. Senkovska, S. Kaskel, D. Volkmer
Dalton Trans., 2017, 46, 6745-6755
DOI: 10.1039/c7dt00582b
Properties of 3D-printed fiber-reinforced Portland cement paste
M. Hambach, D. Volkmer
Cement Concrete Comp., 2017, 79, 62-70
DOI: 10.1016/j.cemconcomp.2017.02.001
Capture of heavy hydrogen isotopes in a metal-organic framework with active Cu(I) sites
I. Weinrauch, I. Savchenko, D. Denysenko, S.M. Souliou, H.-H. Kim, M. Le Tacon, L.L. Daemen, Y. Cheng, A. Mavrandonakis, A.J. Ramirez-Cuesta, D. Volkmer, G. Schütz, M. Hirscher, T. Heine
Nat. Commun., 2017, 8, 14496
DOI: 10.1038/ncomms14496
Cyclic gas-phase heterogeneous process in a metal-organic framework involving a nickel nitrosyl complex
D. Denysenko, D. Volkmer
Faraday Discuss., 2017, 201, 101-112
DOI: 10.1039/C7FD00034K
One-pot synthesis of ultrastable pentanuclear alkylzinc complexes
H. Bunzen, M. Grzywa, A. Kalytta-Mewes, D. Volkmer
Dalton Trans., 2017, 46, 2618-2625
DOI: 10.1039/C6DT04778E
Zr(IV) and Ce(IV)-Based Metal-Organic Frameworks Incorporating 4-Carboxycinnamic Acid as Ligand: Synthesis and Properties
M. SK, M. Grzywa, D. Volkmer, S. Biswas
Microporous Mesoporous Mater., 2017, 237, 275-281
DOI: 10.1016/j.micromeso.2016.09.034
2016
Flexible chiral pyrazolate-based metal-organic framework containing saddle-type CuI4(pyrazolate)4 units
M. Grzywa, D. Denysenko, A. Schaller, A. Kalytta-Mewes, D. Volkmer
CrystEngComm, 2016, 18, 7883-7893
DOI: 10.1039/C6CE01594H
Portland cement paste with aligned carbon fibres exhibiting exceptionally high flexural strength (> 100 MPa)
M. Hambach, H. Möller, T. Neumann, D. Volkmer
Cement Concrete Res., 2016, 89, 80-86
DOI: 10.1016/j.cemconres.2016.08.011
A structurally flexible triazolate-based metal-organic framework featuring coordinatively unsaturated copper(I) sites
P. Schmieder, D. Denysenko, M. Grzywa, O. Magdysyuk, D. Volkmer
Dalton Trans., 2016, 45, 13853-13862
DOI: 10.1039/C6DT02672A
From micro to nano: A toolbox for tuning crystal size and morphology of benzotriazolate-based MOFs
H. Bunzen, M. Grzywa, M. Hambach, S. Spirkl, D. Volkmer
Cryst. Growth Des. 2016, 16, 3190-3197
DOI: 10.1021/acs.cgd.6b00038
Carbon fibre reinforced cement-based composites as smart floor heating materials
M. Hambach, H. Möller, T. Neumann, D. Volkmer
Composites Part B. 2016, 90, 465-470
DOI: 10.1016/j.compositesb.2016.01.043
[Co5Tp*4(Me2bta)6]: A highly symmetrical pentanuclear Kuratowski complex featuring tris(pyrazolyl)borate and benzotriazolate ligands
T. W. Werner, S. Reschke, H. Bunzen, H.-A. Krug von Nidda, J. Deisenhofer, A. Loidl, D. Volkmer,
Inorg. Chem., 2016, 55, 1053-1060
DOI: 10.1021/acs.inorgchem.5b01982
2015
Metal-organic frameworks as host materials of confined supercooled liquids
J.K.H. Fischer, P. Sippel, D. Denysenko, P. Lunkenheimer, D. Volkmer, A. Loidl
J. Chem. Phys. 2015, 143, 154505
DOI: 10.1063/1.4933308
Gas sorption and transition-metal cation separation with a thienothiophene based zirconium metal–organic framework
SK Mostikam, M. Grzywa, D. Volkmer, S. Biswas
J. Solid State Chem. 2015, 232, 221-227
DOI: 10.1016/j.jssc.2015.09.034
Mixed SAMs of Backbone-Functionalized Tribenzotriquinacenes and Alkanethiols: Synthesis, Preparation and STM-Investigations
S. Henne, B. Bredenkötter, D. Volkmer
Appl. Surf. Sci. 2015, 356, 645-650
DOI: 10.1016/j.apsusc.2015.08.106
Carbon supported Ru clusters prepared by pyrolysis of Ru precursor-impregnated biopolymer fibers
A. Kalytta-Mewes, S. Spirkl, S. Tränkle, M. Hambach, D. Volkmer
J. Mater. Chem. A. 2015, 42, 20919-20926
DOI: 10.1039/C5TA04253D
Selective Growth of MFU-4l Single Crystals on Microstructured Plasma Polymer Coatings
A. Schaller, A. Ullrich, S. Horn, D. Volkmer
Chem. Commun. 2015, 51, 12494-12496
DOI: 10.1039/C5CC04048E
CFA-7: An interpenetrated metal-organic framework of the MFU-4 family
P. Schmieder, M. Grzywa, D. Denysenko, M. Hambach, D. Volkmer
Dalton Trans. 2015, 44, 13060-13070
DOI: 10.1039/C5DT01673H
Postsynthetic Metal and Ligand Exchange in MFU-4l: A Screening Approach toward Functional Metal–Organic Frameworks Comprising Single-Site Active Centers
D. Denysenko, J. Jelic, K. Reuter, D. Volkmer
Chem. Eur. J. 2015, 21, 8188-8199
DOI: 10.1002/chem.201406564
Elucidating Lewis acidity of metal sites in MFU-4l metal-organic frameworks: N2O and CO2 adsorption in MFU-4l, CuI-MFU-4l and Li-MFU-4l
D. Denysenko, J. Jelic, O. V. Magdysyuk, K. Reuter, D. Volkmer
Microporous Mesoporous Mater. 2015, 216, 146-150
DOI: 10.1016/j.micromeso.2015.03.014
Fe/Ga-CFA-6 – metal-organic frameworks featuring trivalent metal centers and the 4,4’-bipyrazolyl ligand
S. Spirkl, M. Grzywa, C. Zehe, J. Senker, S. Demeshko, F. Meyer, S. Riegg, D. Volkmer
CrystEngComm. 2015, 17, 313-322
DOI: 10.1039/C4CE01583E
Formation of a Quasi-Solid Structure by Intercalated Noble Gas Atoms in Pores of CuI-MFU-4l Metal-Organic Framework
O. V. Magdysyuk, D. Denysenko, I. Weinrauch, D. Volkmer, M. Hirscher, R. E. Dinnebier
Chem. Commun. 2015, 51, 714-717
DOI: 10.1039/C4CC07554D
2014
Almost Enclosed Buckyball Joints: Synthesis, Complex Formation, and Computational Simulations of Pentypticene-Extended Tribenzotriquinacene
S. Henne, B. Bredenkötter, M. Alaghemandi, S. Bureekaew, R. Schmid, D. Volkmer
Chem. Phys. Chem. 2014, 15, 3855-3863
DOI: 10.1002/cphc.201402475
Calcium carbonate crystal growth beneath Langmuir monolayers of acidic β-hairpin peptides
H. Gong, Y. Yang, M. Pluntke, O. Marti, Z. Majer, N. Sewald, D. Volkmer
Dalton Trans. 2014, 43, 16857-16871
DOI: 10.1039/C4DT01154F
Two 3D Coordination Frameworks Based on Benzobisimidazole Linkers Generated under Similar Conditions: Synthesis, Structures and Thermal Properties
S. Biswas, Y.-Y. Liu, M. Tonigold, M. Weil, D. Volkmer
Eur. J. Inorg. Chem. 2014, 5362-5369
DOI: 10.1002/ejic.201402552
Coordination Frameworks assembled from CuII ions and H2-1,3-bdpb ligands: X-ray and Magneto Structural Investigations, and Catalytic Activity in the Aerobic Oxidation of Tetralin
M. Grzywa, C. Geßner, B. Bredenkötter, D. Denysenko, J. van Leusen, P. Kögerler, E. Klemm, D. Volkmer
Dalton Trans. 2014, 43, 16846-16856
DOI: 10.1039/C4DT01880J
Tribenzotriquinacene Receptors for C60 Fullerene Rotors: Towards C3 Symmetrical Chiral Stators for Unidirectionally Operating Nanoratchets
B. Bredenkötter, M. Grzywa, M. Alaghemandi, R. Schmid, W. Herrebout, P. Bultinck, D. Volkmer
Chem. Eur. J. 2014, 20, 9100-9110
DOI: 10.1002/chem.201304980
Unveiling the mechanism of selective gate-driven diffusion of CO2 over N2 in MFU-4 metal–organic framework
G. Sastre, J. van den Bergh, F. Kapteijn, D. Denysenko, D. Volkmer
Dalton Trans. 2014, 43, 9612-9619
DOI: 10.1039/c4dt00365a
Scorpionate-Type Coordination in MFU-4l Metal–Organic Frameworks: Small-Molecule Binding and Activation upon the Thermally Activated Formation of Open Metal Sites
D. Denysenko, M. Grzywa, J. Jelic, K. Reuter, D. Volkmer
Angew. Chem. 2014, 126, 5942-5946
DOI: 10.1002/ange.201310004
Angew. Chem. Int. Ed. 2014, 53, 5832-5836
DOI: 10.1002/anie.201310004
Dielectric Relaxation Processes, Electronic Structure, and Band Gap Engineering of MFU-4-type Metal-Organic Frameworks: Towards a Rational Design of Semiconducting Microporous Materials
P. Sippel, D. Denysenko, A. Loidl, P. Lunkenheimer, G. Sastre, D. Volkmer
Adv. Funct. Mater. 2014, 24, 3885-3896
DOI: 10.1002/adfm.201400083
2013
Computational screening study towards redox-active metal-organic frameworks
J. Jelic, D. Denysenko, D. Volkmer, K. Reuter
New. J. Phys. 2013, 15, 115004 (12pp)
DOI: 10.1088/1367-2630/15/11/115004
Selective Adsorption of Functionalized Nanoparticles to Patterned Polymer Brush Surfaces and Its Probing with an Optical Trap
A. Steinbach, T. Paust, M. Pluntke, O. Marti, D. Volkmer
Chem. Phys. Chem. 2013, 14, 3523-3531
DOI: 10.1002/cphc.201300516
Sorption and breathing properties of difluorinated MIL-47 and Al-MIL-53 frameworks
S. Biswas, S. Couck, D. Denysenko, A. Bhunai, M. Grzywa, J.F.M. Denayer, D. Volkmer, C. Janiak, P. Van Der Voort
Microporous Mesoporous Mater. 2013, 181, 175-181
DOI: 10.1016/j.micromeso.2013.07.030
Conventional and microwave assisted hydrothermal synthesis of 11 Å tobermorite
S. Tränkle, D. Jahn, T. Neumann, L. Nicoleau, N. Huesing, D. Volkmer
J. Mater. Chem. A 2013, 1, 10318-10326
DOI: 10.1039/C3TA11036B
A Metallosupramolecular Octahedron Assembled from Twelve Cu(I) Metal Ions and Six 4,4'-(1,2-Phenylene)bis(3,5-dimethylpyrazol-1-ide) Ligands
M. Grzywa, B. Bredenkötter, D. Denysenko, S. Spirkl, N. Wojciech, D. Volkmer
Z. Anorg. Allg. Chem. 2013, 639, 1461-1471
DOI: 10.1002/zaac.201300094
CFA-1: the first chiral metal-organic framework containing Kuratowski-type secondary building units
P. Schmieder, D. Denysenko, M. Grzywa, B. Baumgärtner, I. Senkovska, S. Kaskel, G. Sastre, L. van Wüllen, D. Volkmer
Dalton Trans. 2013, 42, 10786-10797
DOI: 10.1039/c3dt50787d
CFA-2 and CFA-3 (Coordination Framework Augsburg University-2 and -3); Novel MOFs Assembled from Trinuclear Cu(I)/Ag(I) Secondary Building Units and 3,3',5,5'-Tetraphenyl-bipyrazolate Ligands
M. Grzywa, C. Gessner, D. Denysenko, B. Bredenkötter, F. Gschwind, K. Fromm, W. Nitek, E. Klemm, D. Volkmer
Dalton Trans. 2013, 42, 6909-6921
DOI: 10.1039/c3dt32302A
Enhanced selectivity of CO2 over CH4 in sulphonate-, carboxylate- and iodo-functionalized UiO-66 frameworks
S. Biswas, J. Zhang, Z. Li, Y.-Y. Liu, M. Grzywa, L. Sun, D. Volkmer, P. Van Der Voort
Dalton Trans. 2013, 42, 4730-4737
DOI: 10.1039/c3dt32288B
Partial fluorinated MIL-47 and Al-MIL-53 frameworks: influence of functionalization on sorption and breathing properties
S. Biswas, T. Rémy, S. Couck, D. Denysenko, G. Rampelberg, J. F. M. Denayer, D. Volkmer, C. Detavernier, P. Van Der Voort
Phys. Chem. Chem. Phys. 2013, 15, 3552-3561
DOI: 10.1039/c3cp44204g
New VIV-Based Metal-Organic Framework Having Framework Flexibility and High CO2 Adsorption Capacity
Y.-Y. Liu, S. Couck, M. Vandichel, M. Grzywa, K. Leus, S. Biswas, D. Volkmer, J. Gascon, F. Kapteijn, J. F. M. Denayer,M. Waroquier, V. Van Speybroeck, P. Van Der Voort
Inorg. Chem. 2013, 52, 113-120
DOI: 10.1021/ic301338a
MFU-4 - A Metal-Organic Framework for Highly Effective H2/D2 Separation
J. Teufel, H. Oh, M. Hirscher, M. Wahiduzzaman, L. Zhechkov, A. Kuc, T. Heine, D. Denysenko, D. Volkmer
Adv. Mater. 2013, 4, 635-639
DOI: 10.1002/adma.201203383
2012
Novel characterization of the adsorption sites in large pore metal-organic frameworks: combination of X-ray powder diffraction and thermal desorption spectroscopy
A. Soleimani-Dorcheh, R. E. Dinnebier, A. Kuc, O. Magdysyuk, F. Adams, D. Denysenko, T. Heine, D. Volkmer, W. Donner, M. Hirscher
Phys. Chem. Chem. Phys. 2012, 14, 12892-12897
DOI: 10.1039/C2CP41344B
Microdomain Transformations in Mosaic Mesocrystal Thin Films
Y. Jiang, H. Gong, M. Grzywa, D. Volkmer, L. Gower, H. Cölfen
Adv. Funct. Mat. 2012, 23, 1547-1555
DOI: 10.1002/adfm.201202294
Plasma Enhanced Chemical Vapor Deposition of n-Heptane and Methyl Methacrylat for Potential Cell Alignment Applications
A. Steinbach, A. Tautzenberger, A. Schaller, A. Kalytta, S. Tränkle, A. Ignatius, D. Volkmer
Appl. Mater. Interfaces 2012, 4, 5196-5203
DOI: 10.1021/am301124b
A 12-connected metal-organic framework constructed from an unprecedented cyclic dodecanuclear copper cluster
H. Zhang, Y. Lu, Z. Zhang, H. Fu, Y. Li, D. Volkmer, D. Denysenko, E. Wang
Chem. Commun. 2012, 48, 7292-7297
DOI: 10.1039/c2cc32120c
Nobel gases and microporous frameworks; from intercation to application
A. S. Dorcheh, D. Denysenko, D. Volkmer, W. Donner, M. Hirscher
Micropor. Mesopor. Mat. 2012, 162, 64-68
DOI: 10.1016/j.micromeso.2012.06.004
Vanadium Analogues of Nonfunctionalized and Amino-Functionalized MOFs with MIL-101 Topology - Synthesis, Characterization, and Gas Sorption Properties
S. Biswas, S. Couck, M. Grzywa, J. F. M. Denayer, D. Volkmer, P. Van Der Voort
Eur. J. Inorg. Chem. 2012, 2481-2486
DOI: 10.1002/ejic.201200106
Advanced buckyball joints: synthesis, complex formation and computational simulations of centrohexaindane-extended tribenzotriquinacene receptors for C60 fullerene
S. Henne, B. Bredenkötter, A. A. D. Baghi, R. Schmid, D. Volkmer
Dalton Trans. 2012, 41, 5995-6002
DOI: 10.1039/C2DT12435A
Production of CaCO3/hyperbranched polyglycidol hybrid films using spray-coating technique
K. Malinova, M. Gunesch, S. M. Pancera, R. Wengeler, B. Rieger, D. Volkmer
J. Colloid Interface Sci. 2012, 374, 61-69
DOI: 10.1016/j.jcis.2012.02.011
CuN6 Jahn-Teller centers in coordination frameworks comprising fully condensed Kuratowski-type secondary building units: phase transitions and magneto-structural correlations
M. Grzywa, D. Denysenko, J. Hanss, E.-W. Scheidt, W. Scherer, M. Weil, D. Volkmer
Dalton Trans. 2012, 41, 4239-4248
DOI: 10.1039/C2DT12311H
Coatings from micropatterned sulfobetaine polymer brushes as substrates for MC3T3-E1 cells
A. Steinbach, A. Tautzenberger, A. Ignatius, M. Pluntke, O. Marti, D. Volkmer
J. Mater. Sci.: Mater. Med. 2012, 23, 573-579
DOI: 10.1007/s10856-011-4525-y
Synthesis, Structural Characterization, and Catalytic Performance of a Vanadium-Based Metal-Organic Framework (COMOC-3)
Y.-Y. Liu, K. Leus, M. Grzywa, D. Weinberger, K. Strubbe, H. Vrielinck, R. Van Deun, D. Volkmer, V. Van Speybroeck, P. Van Der Voort
Eur. J. Inorg. Chem. 2012, 2819-2827
DOI: 10.1002/ejic.201101099
The existence region and composition of a polymer-induced liquid precursor phase for DL-glutamatic acid crystals
Y. Jiang, L. Gower, D. Volkmer, H. Cölfen
Phys. Chem. Chem. Phys. 2012, 14, 914-919
DOI: 10.1039/C1CP21862J
Reversible gas-phase redox processes catalyzed by Co-exchanged MFU-4l(arge)
D. Denysenko, T. Werner, M. Grzywa, A. Puls, V. Hagen, G. Eickerling, J. Jelic, K. Reuter, D. Volkmer
Chem. Commun. 2012, 48, 1236-1238
DOI: 10.1039/C2CC16235K
2011
Preparation of Hierarchical Mesocrystalline DL-Lysine HCl-Poly(acrylic acid) Hybrid Thin Films
Y. Jiang, H. Gong, D. Volkmer, L. Gower, H. Cölfen
Adv. Mat. 2011, 23, 3548-3552
DOI: 10.1002/adma.201101468
Pyrazolate-Based Cobalt(II)-Containing Metal-Organic Frameworks in Heterogeneous Catalytic Oxidation Reactions: Elucidating the Role of Entatic States for Biomimetic Oxidation Processes
M. Tonigold, Y. Lu, A. Mavrandonakis, A. Puls, R. Staudt, J. Möllmer, J. Sauer, D. Volkmer
Chem. Eur. J. 2011, 17, 8671-8695
DOI: 10.1002/chem.201003173
Hierachical DL-Glutamic Acid Microspheres from Polymer-Induced Liquid Precursors
Y. Jiang, L. Gower, D. Volkmer, H. Cölfen
Cryst. Growth Des. 2011, 11, 3243-3249
DOI: 10.1021/cg200504n
3D characterization of microstructured poly(methacrylic acid) thin films via Mach-Zehnder interference microscopy
S. Letsche, P. Jacobs, M. Pluntke, S. Tränkle, H. Gong, O. Marti, D.M. Mahlmann, P. Loosen, D. Volkmer
Thin Solid Films 2011, 519, 8100-8108
DOI: 10.1016/j.tsf.2011.05.045
Photophysical properties of Kuratowski-type coordination compounds [MIIZn4Cl4(Me2bta)6] (MII = Zn or Ru) featuring long-lived excited electronic states
Y.-Y. Liu, M. Grzywa, M. Tonigold, G. Sastre, T. Schüttrigkeit, N.S. Leeson, D. Volkmer
Dalton Trans. 2011, 40, 5926-5938
DOI: 10.1039/C0DT01750G
Elucidating Gating Effects for Hydrogen Sorption in MFU-4-Type Triazolate-Based Metal–Organic Frameworks Featuring Different Pore Sizes
D. Denysenko, M. Grzywa, M. Tonigold, B. Streppel, I. Krkljus, M. Hirscher, E. Mugnaioli, U. Kolb, J. Hanss, D. Volkmer
Chem. Eur. J. 2011, 17, 1837–1848
DOI: 10.1002/chem.201001872
2010
Thermal spin-crossover in the [M3Zn6Cl6L12] (M = Zn, FeII; L = 5,6-dimethoxy-1,2,3-benzotriazolate) system: structural, electrochemical, Mössbauer, and UV-Vis spectroscopic studies
S. Biswas, M. Tonigold, H. Kelm, H.-J. Krüger, D. Volkmer
Dalton Trans. 2010, 39, 9851-9859
DOI: 10.1039/C0DT00556H
Syntheses and magnetostructural investigations on kuratowski-type homo-and heteropentanuclear coordination compounds [MZn4Cl4(L)6] (MII = Zn, Fe, Co, Ni, or Cu; L = 5,6-Dimethyl-1,2,3- benzotriazolate) represented by the nonplanar K3,3 graph
S.Biswas, M. Tonigold, M. Speldrich, P. Kögerler, M. Weil, D. Volkmer
Inorg. Chem. 2010, 49, 7424–7434
DOI: 10.1021/ic100749k
Comparative solvolytic stabilities of copper(II) nanoballs and dinuclear Cu(II) paddle wheel units
M. Tonigold, D. Volkmer
Inorg. Chim. Acta 2010,363, 4220-4229
DOI: 10.1016/j.ica.2010.06.022
[Cu4OCl6(DABCO)2] · 0.5DABCO · 4CH3OH (‘‘MFU-5’’): Modular synthesis of a zeolite-like metal-organic framework constructed from tetrahedral {Cu4OCl6} secondary building units and linear organic linkers
Y.-Y. Liu, M. Grzywa, M. Weil, D. Volkmer
J. Solid State Chem. 2010, 183, 208-217
DOI: 10.1016/j.jssc.2009.10.026
A Supramolecular Compound Mimicking the Cu- Containing Active Site of pMMO enzyme
M. Grzywa, B. Bredenkötter, D. Volkmer, W. Nitek, J. Sonntag, E. Klemm
Acta Cryst. A. 2010, A66, s241-s242
DOI: 10.1107/S0108767310094535
Multilayered CaCO3/block-copolymer materials via amorphous precursor to crystal transformation
H. Gong, M. Pluntke, O. Marti, P. Walther, L. Gower, H. Cölfen, D. Volkmer
Coll. Surf. A 2010, 354, 279-283
DOI: 10.1016/j.colsurfa.2009.08.002
Thermal spin-crossover in the [M3Zn6Cl6L12] (M = Zn, FeII; L = 5,6-dimethoxy-1,2,3-benzotriazolate) system: structural, electrochemical, Mössbauer, and UV-Vis spectroscopic studies
S. Biswas, M. Tonigold, H. Kelm, H.-J. Krüger, D. Volkmer
Dalton Trans. 2010, 39, 9851-9859
DOI: 10.1039/C0DT00556H
2009
Heterogeneous Catalytic Oxidation by MFU-1: A Cobalt(II)-Containing Metal-Organic Framework
M. Tonigold, Y. Lu, B. Bredenkötter, B. Rieger, S. Bahnmüller, J. Hitzbleck, G. Langstein, D. Volkmer
Angew. Chem. 2009, 121, 7682–7687
DOI: 10.1002/ange.200901241
Angew. Chem. Int. Ed. Engl.2009, 48, 7546–7550
DOI: 10.1002/anie.200901241
A cubic coordination framework constructed from benzobistriazolate ligands and zinc ions having selective gas sorption properties
S. Biswas, M. Grzywa, H. P. Nayek, S. Dehnen, I. Senkovska, S. Kaskel, D. Volkmer
Dalton Trans. 2009, 6487-6495
DOI: 10.1039/b904280f
Nonanuclear Coordination Compounds Featuring {M9L12}6+ Cores (M = NiII, CoII, or ZnII; L = 1,2,3-Benzotriazolate)
S. Biswas, M. Tonigold, M. Speldrich, P. Kögerler, D. Volkmer
Eur. J. Inorg. Chem. 2009, 3094-3101
DOI: 10.1002/ejic.200900156
Copper(II) Nanoballs as monomers for polyurethane coatings: synthesis, urethane derivatization and kinetic stability
M. Tonigold, J. Hitzbleck, S. Bahnmüller, G. Langstein, D. Volkmer
Dalton Trans. 2009, 1363-1371
DOI: 10.1039/b811004b
Synthesis of terpyridine-substituted calix[n]arenes
J. Liu, M. Tonigold, B. Bredenkötter, T. Schröder, J. Mattay, D. Volkmer
Tetr. Lett. 2009, 50, 1303-1306
DOI: 10.1016/j.tetlet.2009.01.044
Usage of Polymer Brushes as Substrates of Bone Cells
S. A. Letsche, A. M. Steinbach, M. Pluntke, O. Marti, A. Ignatius, D. Volkmer
Front. Mater. Sci. China 2009, 3, 132-144
DOI: 10.1007/s11706-009-0035-y
2008
Homo- and Heteropentanuclear Coordination Compounds with Td Symmetry - the Solid State Structures of
[MZn4(L)4(L')6] (M = CoII or Zn; L = chloride or acac; L'= 1,2,3-benzotriazolate)
S. Biswas, M. Tonigold, D. Volkmer
Z. Anorg. Allg. Chem. 2008, 634, 2532-2538
DOI: 10.1002/zaac.200800296
A Cobalt(II)-containing Metal-organic framework Showing Catalytic Activity in Oxidation Reactions
Y. Lu, M. Tonigold, B. Bredenkötter, D. Volkmer, J. Hitzbleck, G. Langstein
Z. Anorg. Allg. Chem. 2008, 634, 2411-2417
DOI: 10.1002/zaac.200800158
A self-assembling metallosupramolecular cage based on cavitand–terpyridine subunits
T. Schröder, R. Brodbeck, M. C. Letzel, A. Mix, B. Schnatwinkel, M. Tonigold, D. Volkmer, J. Mattay
Tetr. Lett. 2008, 49, 5939-5942
DOI: 10.1016/j.tetlet.2008.07.143
Metal-organic frameworks (MOFs) based on zinc triptycene-dicarboxylate
S. Vagin, A. Ott, H.-C. Weiss, A. Karbach, D. Volkmer, B. Rieger
Eur. J. Inorg. Chem. 2008, 2601-2609
DOI: 10.1002/ejic.200701335
Isolated and linear Arrays of Surfactant-encapsulated Polyoxometalate Clusters on Graphite
P. Wu, D. Volkmer, B. Bredenkötter, D.G. Kurth, J.P. Rabe
Langmuir 2008, 24, 2767-2771
DOI: 10.1021/la7032143
Molecular dynamics simulations of dendrimer-encapsulated alpha-Keggin ions in trichloromethane solution
R. Brodbeck, D. Andrae, T. Toensing, D. Volkmer
J. Phys. Chem. B 2008, 112, 5153-5162
DOI: 10.1021/jp710215u
2007
Nanosized Ball Joints Constructed from C60 and Tribenzotriquinacene Sockets: Synthesis, Component Self-Assembly and Structural Investigations
B. Bredenkötter, S. Henne, D. Volkmer
Chem. Eur. J. 2007, 13, 9931–9938
DOI: 10.1002/chem.200700915
Self-Assembly of Amphiphilic Hexapyridinium Cations at the Air/Water Interface and on HOPG Surfaces
H. Gong, B. Bredenkötter, C. Meier, C. Hoffmann- Richter, U. Ziener, D.G. Kurth, D. Volkmer
ChemPhysChem 2007, 8, 2354–2362
DOI: 10.1002/cphc.200700233
Biologically Inspired Crystallization of Calcium Carbonate beneath Monolayers: A Critical Overview.
D. Volkmer in: Handbook of Biomineralization, 1st ed., Vol. 2, Chapter 4 (E. Bäuerlein, P. Behrens, M. Epple, eds.), Wiley-VCH 2007
Nanometer-Sized Molybdenum–Iron Oxide Capsule- Surface Modifications: External and Internal
A. Müller, H. Bögge, F.L. Sousa, M. Schmidtmann, D.G. Kurth, D. Volkmer, J. van Slageren, M. Dressel, M. L. Kistler, T. Liu
Small 2007, 3, 986–992
DOI: 10.1002/smll.200600567
Formation of Single-Crystalline Aragonite Tablets/Films via an Amorphous Precursor
F.F. Amos, D.M. Sharbaugh, D.R. Talham, L.B. Gower, M. Fricke, D. Volkmer
Langmuir 2007, 23, 1988–1994
DOI: 10.1021/la061960n
Synthesis of Poly(methacrylic acid) Brushes via Surface-Initiated Atom Transfer Radical Polymerization of Sodium Methacrylate and Their Use as Substrates for the Mineralization of Calcium Carbonate
S. Tugulu, R. Barbey, M. Harms, M. Fricke, D. Volkmer, A. Rossi, H.-A. Klok
Macromolecules 2007, 40, 168–177
DOI: 10.1021/ma060739e
Two-dimensional metal–organic frameworks (MOFs) constructed from heterotrinuclear coordination units and 4,4'-biphenyldicarboxylate ligands
Y. Wang, B. Bredenkötter, B. Rieger, D. Volkmer
Dalton Trans. 2007, 689–696
DOI: 10.1039/b609733b
Crystallization of Calcium Carbonate Beneath Insoluble Monolayers: SuitableModels of Mineral–Matrix Interactions in Biomineralization?
M. Fricke, D. Volkmer
Top. Curr. Chem. 2007, 270, 1–41
DOI: 10.1007/128_063
Novel palladium complexes employing mixed phosphine phosphonates and phosphine phosphinates as anionic chelating [P,O] ligands
C.M. Reisinger, R.J. Nowack, D. Volkmer, B. Rieger
Dalton Trans. 2007, 272–278
DOI: 10.1039/b612694d
2006
Reliable stabilization and functionalization of nanoparticles through tridentate thiolate ligands
K. Wojczykowski, D. Meißner, P. Jutzi, I. Ennen, A. Hütten, M. Fricke, D. Volkmer
Chem. Commun., 2006, 3693–3695
DOI: 10.1039/b606360h
Polymer Brushes as Ionotropic Matrices for the Directed Fabrication of Microstructured Calcite Thin Films
S. Tugulu, M. Harms, M. Fricke, D. Volkmer, H.-A. Klok
Angew. Chem. 2006, 118, 7619–7623
DOI: 10.1002/ange.200602382
Angew. Chem. Int. Ed. Engl. 2006, 45, 7458–7461
DOI: 10.1002/anie.200602382
Crystal Structure Analysis of [Ca(O3SC18H37)2(DMSO)2], a Lamellar Coordination Polymer and its Relevance for Model Studies in Biomineralization
D. Volkmer, N. Mayr, M. Fricke
Dalton Trans. 2006, 4889–4895
DOI: 10.1039/b608760d
Vaterite Polymorph Switching Controlled by Surface Charge Density of an Amphiphilic Dendron-calix[4]arene
M. Fricke, D. Volkmer, C.E. Krill III, M. Kellermann, A. Hirsch
Cryst. Growth Des. 2006, 6, 1120–1123
DOI: 10.1021/cg050534h
Polyoxometalate-Based Electro- and Photochromic Dual-Mode Devices
S. Liu, H. Möhwald, D. Volkmer, D.G. Kurth
Langmuir 2006, 22, 1949–1951
DOI: 10.1021/la0523863
2005
Elucidating the role of charge density on the growth of CaCO3 crystals underneath calix[4]arene monolayers
D. Volkmer, M. Fricke, M. Gleiche, L.F. Chi
Mater. Sci. Eng. C 2005, 25, 161–167
DOI: 10.1016/j.msec.2005.01.006
Morphosynthesis of Nacre-Type Laminated CaCO3 Thin Films and Coatings
D. Volkmer, M. Harms, L. Gower, A. Ziegler
Angew. Chem. 2005, 117, 645–650
DOI: 10.1002/ange.200461386
Angew. Chem. Int. Ed. Engl. 2005, 44, 639 –644
DOI: 10.1002/anie.200461386
2004
Coordination arrays - Synthesis and characterization of tetranuclear complexes of grid-type
G.S. Hanan, D. Volkmer, J.-M. Lehn
Can.J. Chem. 2004, 82, 1428–1434
DOI: 10.1139/V04-092
From molecular modules to modular materials
S.Q. Liu, D. Volkmer, D.G. Kurth
Pure Appl. Chem. 2004, 76, 1847–1867
DOI: 10.1351/pac200476101847
Dynamics and Equilibrium of the Penetration of Soluble Cetyltrimethylammonium Bromide into Langmuir Monolayers of Arachidic Acid under Different pH Conditions
V.B. Fainerman, D. Vollhardt, A. Roth, M. Fricke, D. Volkmer
J. Phys. Chem. B 2004, 108, 16163–16167
DOI: 10.1021/jp040070i
Interfacial electrostatics guiding the crystallization of CaCO3 underneath monolayers of calixarenes and resorcarenes
D. Volkmer, M. Fricke, C. Agena, J. Mattay
J. Mater. Chem. 2004, 14, 2249–2259
DOI: 10.1039/b403132f
Acidic peptides acting as growth modifiers of calcite crystals
D. Volkmer, M. Fricke, T. Huber, N. Sewald
Chem. Commun. 2004, 1872–1873
DOI: 10.1039/b405613b
Smart Polyoxometalate-Based Nitrogen Monoxide Sensors
S.Q. Liu, D. Volkmer, D.G. Kurth
Anal. Chem. 2004, 76, 4579–4582
DOI: 10.1021/ac0495283
2003
Biomimetische Strategien zum Aufbau funktionaler Materialien: von Dendrizymen zu künstlichen Radiolarienschalen
D. Volkmer, Habilitationsschrift, Bielefeld 2003
Polyoxometalate Nanoclusters in Tailored Architectures: From Structure to Function
S. Liu, D.G. Kurth, D. Volkmer, in Polyoxometalate Molecular Science, Eds.: J.J. Borrás-Almenar, E. Coronado, A. Müller, M.T. Pope
NATO SCIENCE SERIES II: Mathematics, Physics and Chemistry, Vol. 98,
Kluwer Academic Publishers, Dordrecht 2003
Functional Polyoxometalate Thin Films via Electrostatic Layer-by-Layer Self-Assembly
S. Liu, D. Volkmer, D.G. Kurth
J. Clust. Sci. 2003, 14, 405–419
DOI 10.1023/B:JOCL.0000005072.28928.96
Growth of Calcite Single Crystals Underneath Monolayers of 5,11,17,23-Tetra-t-butyl-25,26,27,28-tetrakis(carboxymethoxy)- calix[4]arene
D. Volkmer, M. Fricke,
Z. Anorg. Allg. Chem. 2003, 629, 2381–2390
DOI: 10.1002/zaac.200300254
Morphosynthesis of Star-Shaped Titania-Silica Shells
D. Volkmer, S. Tugulu, M. Fricke, T. Nielsen
Angew. Chem. 2003, 115, 60–64
DOI: 10.1002/ange.200390022
Angew. Chem. Int. Ed. Engl 2003, 42, 58–61
DOI: 10.1002/anie.200390051
2002
Multilayers on Solid Planar Substrates: From Structure to Function
D.G. Kurth, D. Volkmer, R.v. Klitzing, in Multilayer Thin Films – Sequential Assembly of Nanocomposite Materials,
Eds.: G. Decher, J.B. Schlenoff, Wiley-VCH, Weinheim 2002, 393–426
Crystallization of (012) Oriented Calcite Single Crystals under Monolayers of Tetra(carboxymethoxy)calix[4]arenes
D. Volkmer, M. Fricke, D. Vollhardt, S. Siegel
J. Chem. Soc., Dalton Trans. 2002, 4547–4544
DOI: 10.1039/b206912a
Structure and Properties of the Dendron-Encapsulated Polyoxometalate (C52H60NO12)12[(Mn(H2O))3(SbW9O33)2], a First Generation Dendrizyme
D. Volkmer, B. Bredenkötter, J. Tellenbröker, P. Kögerler, D.G. Kurth, P. Lehmann, H. Schnablegger, D. Schwahn, M. Piepenbrink, B. Krebs
J. Am. Chem. Soc. 2002, 124, 10489–10496
DOI: 10.1021/ja017613b
Oriented Crystallization of Calcite Single Crystals Grown Underneath Monolayers of Tetracarboxyresorc[4]arenes
D. Volkmer, M. Fricke, C. Agena, J. Mattay
Cryst. Eng. Comm. 2002, 4, 288–295
DOI: 10.1039/b202208g
Polyoxometalates as pH-sensitive probes in self-assembled multilayers
S. Liu, D.G. Kurth, D. Volkmer,
Chem. Commun. 2002, 976–977
DOI: 10.1039/b200942k
A Thin-Film Electrochromic Device Based on a Polyoxometalate Cluster
S. Liu, D.G. Kurth, H. Möhwald, D. Volkmer
Adv. Mater. 2002, 14, 225–228
DOI: 10.1002/1521-4095(20020205)14:3<225::AID-ADMA225>3.0.CO;2-F
The Structure of Self-Assembled Multilayers with Polyoxometalate Nanoclusters
S. Liu, D. G. Kurth, B. Bredenkötter, D. Volkmer
J. Am. Chem. Soc. 2002, 124, 12279–12287
DOI: 10.1021/ja026946
Von Biomineralien zu biomimetischen Materialien
D. Volkmer
10. Heiligenstädter Kolloquium (Technische Systeme für Biotechnologie und Umwelt – Biosensorik und Zellkulturtechnik), Deutsche Bundesstiftung Umwelt, Erich Schmidt Verlag, Berlin, 2002, pp.107–118
2001
Polyoxometalate clusters in a supramolecular self-organized environment: Steps towards functional nanodevices and thin film applications
D.G. Kurth and D. Volkmer in Polyoxometalate Chemistry: From Topology via Self-Assembly to Applications , (A. Müller, M.T. Pope, eds.), Kluwer Academic Publishers, Dordrecht, 2001, pp. 301–318
2000
Biologically inspired polyoxometalate-surfactant composite materials. Investigations on the structures of discrete, surfactant-encapsulated clusters, monolayers, and Langmuir-Blodgett films of (DODA)40(NH4)2[(H2O)nMo132O372 (CH3CO2)30(H2O)72]
D.G. Kurth, P. Lehmann, D. Volkmer, A. Müller, D. Schwahn
J. Chem. Soc., Dalton Trans. 2000, 3989–3998
DOI: 10.1039/b003331f
S- and NH-Bridging Pyridine- and Pyrimidine-Based Ligands for 2x2, 3x3 and 4x4 Molecular Grids: Evidence of [2x2]Zn(II) Grids
T. Tuntulani, G. Tumcharern, D. Volkmer
Bull. Korean Chem. Soc. 2000, 21, 1245–1248
Ultrathin composite films incorporating the nanoporous isopolyoxomolybdate “Keplerate” (NH4)42[Mo132O372(CH3COO)30(H2O)72]
D.G. Kurth, D. Volkmer, M. Ruttorf, B. Richter, A. Müller
Chem. Mater. 2000, 12, 2829–2831
DOI: 10.1021/cm001032o
Biomineralization
D. Volkmer in Encyclopedia of Separation Science (M. Cooke, C.F. Poole, eds.), Vol. 2 (Crystallization), Academic Press, (2000 ), pp.940–950
Toward nanodevices: Synthesis and characterization of the nanoporous surfactant-encapsulated Keplerate (DODA)40(NH4)2[(H2O)nMo1320372(CH3COO)30(H2O)72]
D. Volkmer, A. Du Chesne, D.G. Kurth, H. Schnablegger, P. Lehmann, M.J. Koop, A. Müller
J. Am. Chem. Soc. 2000, 122, 1995–1998
DOI: 10.1021/ja992350v
Surfactant-encapsulated clusters (SECs): (DODA)20(NH4)[H3Mo57V6(NO)6O183 (H2O)18], a case study
D.G. Kurth, P. Lehmann, D. Volkmer, H. Cölfen, M.J. Koop, A. Müller, A. Du Chesne
Chem. Eur. J. 2000, 6, 385–393
DOI: 10.1002/(SICI)1521-3765(20000117)6:2<385::AID-CHEM385>3.0.CO;2-A
1993-1999
Synthesis and characterization of homo- and heterodinuclear complexes containing the N3M(µ2-SR)3MN3 core (M = Fe, Co, Ni)
B. Kersting, D. Siebert, D. Volkmer , M.J. Kolm, C. Janiak
Inorg. Chem. 1999, 38, 3871–3882
DOI: 10.1021/ic990087t
Von Biomineralien zu biomimetischen Materialien: Der Weg ist das Ziel
D. Volkmer
Chem. Uns. Zeit 1999, 33, 6–19
DOI: 10.1002/ciuz.19990330103
Complexes of Ni(II) and Zn(II) as models for hydrolytic enzymes
H. Schwöppe, D. Volkmer, B. Krebs
J. Inorg. Biochem. 1999, 74, 292
Model complexes for ureases: A dinickel(II) complex with a novel asymmetric ligand and comparative kinetic studies on catalytically active zinc, cobalt, and nickel complexes
B. Hommerich, H. Schwöppe, D. Volkmer , B. Krebs
Z. Anorg. Allg. Chem. 1999, 625, 75–82
DOI: 10.1002/(SICI)1521-3749(199901)625:1<75::AID-ZAAC75>3.0.CO;2-X
Ultrathin molybdenum polyoxometalate–polyelectrolyte multilayer films
F. Caruso, D.G. Kurth, D. Volkmer, M.J. Koop, A. Müller
Langmuir 1998, 14, 3462–3465
DOI: 10.1021/la980177v
Magnetism of self-assembled mono- and tetranuclear supramolecular Ni2+ complexes
O. Waldmann, J. Hassmann, P. Müller, D. Volkmer, U.S. Schubert, J.-M. Lehn
Phys. Rev. B 1998, 58, 3277–3285
DOI: 10.1103/PhysRevB.58.3277
Magnetic supramolecular grid structures: Intramolecular coupling of four separate spins
O. Waldmann, J. Hassmann, R. Koch, P. Müller, G.S. Hanan, D. Volkmer, U.S. Schubert, J.-M. Lehn
Mat. Res. Soc. Symp. Proc. 1998, 448, 841–846
DOI: 10.1557/PROC-488-841
Structural and electronic properties of self-assembled supramolecular grid structures: Doping of supramolecular thin films
J. Hassmann, C.Y. Hahn, O. Waldmann, E. Volz, H.-J. Schleemilch, N. Hallschmid, P. Müller, G.S. Hanan, D. Volkmer, U.S. Schubert, J.-M. Lehn, H. Mauser, A. Hirsch
Mat. Res. Soc. Symp. Proc. 1998, 448, 447–452
DOI: 10.1557/PROC-488-447
Design of coordination arrays as potential molecular memory units and switches
G.S. Hanan, U.S. Schubert, D. Volkmer , J.-M. Lehn, J. Hassmann, C.Y. Hahn, O. Waldmann, P. Müller, G. Baum, D. Fenske, in“9th International Symposium on Molecular Recognition and Inclusion”, A.W. Coleman (ed.), pp.349–352, Kluwer Academic Publishers, Dordrecht 1998
Coordination arrays: Tetranuclear cobalt(II) complexes with [2×2]-grid structure
G.S. Hanan, D. Volkmer, U.S. Schubert, J.-M. Lehn, G. Baum, D. Fenske
Angew. Chem. 1997, 109 , 1929–1931
DOI: 10.1002/ange.19971091710
Angew. Chem. Int. Ed. Engl. 1997, 36, 1842–1844
DOI: 10.1002/anie.199718421
Novel N-donor heterocyclic ligands and their coordination chemistry towards a Cu(II) salt
T. Tuntulani, D. Volkmer, D. Fenske, J.-M. Lehn
J. Sci. Soc. Thailand, 1997, 23, 185–198
DOI: 10.2306/scienceasia1513-1874.1997.23.185
Intramolecular antiferromagnetic coupling in supramolecular grid structures with Co2+ metal centers
O. Waldmann, J. Hassmann, P. Müller, G.S. Hanan, D. Volkmer, U.S. Schubert, J.-M. Lehn
Phys. Rev. Lett. 1997, 78, 3390–3393
DOI: 10.1103/PhysRevLett.78.3390
Synthesis, structure, and properties of oligo-tridentate ligands; covalently assembled precursors of coordination arrays
G.S. Hanan, U.S. Schubert, D. Volkmer , E. Rivière, J.-M. Lehn, N. Kyritsakas, J. Fischer
Can. J. Chem. 1997 , 75, 169–182
DOI: 10.1139/v97-020
Dinuclear nickel(II) complexes as models for the active site of urease
D. Volkmer, B. Hommerich, K. Griesar, W. Haase, B. Krebs,
Inorg. Chem. 1996, 35, 3792–3803
DOI: 10.1021/ic951567x
[Ni2(ppepO)(C6H5COO)2(CH3COOH)]ClO4 · C4H10O: Synthesis and characterization of an asymmetric dinuclear nickel(II) complex showing unusual coordination behavior with relevance to the active site of urease
D.Volkmer, A. Hörstmann, K. Griesar, W. Haase, B. Krebs
Inorg. Chem. 1996, 35, 1132–1134
DOI: 10.1021/ic950368a
Dinuclear Ni(II) complexes as models for the active site of urease
D.Volkmer, B. Krebs
J. Inorg. Biochem. 1993, 51, 511
DOI: 10.1016/0162-0134(93)85539-K